11 year papers

Coordination Compounds JEE Main PYQ Chapter Wise (2016–2026)

Coordination Compounds JEE Main PYQs: all 18 questions from 11 official papers (2016–2026), by concept with official answers. Asked in 3 of 3 years.

Updated2 min read
Full name
Joint Entrance Examination Main
Conducted by
NTA
Frequency
Multiple sessions per year
Sections
Physics · Chemistry · Mathematics
Official site
jeemain.nta.nic.in ↗

Explore: All JEE Main chapters · JEE Main Chemistry PYQs · JEE Main hub · JEE Main 2026 · Syllabus & pattern

Answer first

Coordination Compounds PYQs (previous year questions) for JEE Main: Coordination Compounds (Chemistry) had 18 questions across the 11 official JEE Main papers we tagged (2016–2026), and appeared in 11 of them. Asked in 3 of 3 years. The concepts asked in the most papers: Crystal Field Theory, Werner’s Theory, Isomerism in Complexes.

Year-wise question count

Asked in 3 of 3 years.

YearPapersQuestionsPer paper
JEE Main 20269151.7
JEE Main 2017111
JEE Main 2016122

Most-asked concepts

Sorted by the number of papers a concept appeared in.

ConceptQuestionsPapersYears
Crystal Field Theory552026
Werner's Theory332026, 2017
Crystal Field Splitting222026
Isomerism in Complexes222026, 2016
Magnetic Moment112016
Magnetic Moment of Complexes112026
Magnetic Properties112026
Metal Carbonyls112026
Stability and Isomerism112026
Valence Bond Theory112026

How to practise Coordination Compounds PYQs

  1. Start with the concepts at the top of the table. They have come back the most.
  2. Solve one year’s Coordination Compounds questions from the official PDF against the clock, then check the answer listed below.
  3. Log every miss as a concept gap, a calculation slip or a misread. Each needs a different fix.
  4. Once a concept is clean in two papers, move to the next. Then sit a full paper from the year pages.

Questions by year

Each line gives the question number and paper, type, concept, our one-line summary and the official answer, with a link to the official PDF.

JEE Main2026

  • Q.62 (2 April, shift 1) · MCQ · Crystal Field Theory: Match Cr(III) complexes with their crystal field splitting values (official answer: option 4) PDF
  • Q.71 (2 April, shift 1) · Numerical · Werner's Theory: Mole ratio of complex to AgCl for CrCl3.6H2O after ion exchange (official answer: 33) PDF
  • Q.61 (2 April, shift 2) · MCQ · Isomerism in Complexes: Identify complexes showing coordination isomerism (official answer: option 2) PDF
  • Q.62 (4 April, shift 1) · MCQ · Magnetic Moment of Complexes: Match aqua complexes with their spin-only magnetic moments (official answer: option 4) PDF
  • Q.60 (4 April, shift 2) · MCQ · Crystal Field Theory: Unpaired electrons and absorption frequency order of three Ni complexes (official answer: option 1) PDF
  • Q.61 (5 April, shift 1) · MCQ · Metal Carbonyls: Correct statements on bonding in metal carbonyls (official answer: option 2) PDF
  • Q.62 (5 April, shift 1) · MCQ · Crystal Field Theory: Statements on crystal field splitting energies and degeneracy (official answer: option 1) PDF
  • Q.60 (5 April, shift 2) · MCQ · Crystal Field Splitting: Statements on atomisation enthalpy and d-orbital splitting in complexes (official answer: option 1) PDF
  • Q.61 (5 April, shift 2) · MCQ · Stability and Isomerism: Correct statements on complex stability, hybridisation, linkage isomerism (official answer: option 3) PDF
  • Q.71 (5 April, shift 2) · Numerical · Crystal Field Theory: Total unpaired electrons in high- and low-spin octahedral d-configurations (official answer: 15) PDF
  • Q.61 (6 April, shift 1) · MCQ · Crystal Field Theory: Match tetrahedral d^n configurations with CFSE values (official answer: option 3) PDF
  • Q.62 (6 April, shift 1) · MCQ · Crystal Field Splitting: Energy order of d-orbitals in a tetrahedral complex (official answer: option 1) PDF
  • Q.61 (6 April, shift 2) · MCQ · Valence Bond Theory: Hybridisation, geometry and magnetism of nickel complexes (official answer: option 4) PDF
  • Q.71 (6 April, shift 2) · Numerical · Werner's Theory: Moles of AgCl precipitated from a chromium aqua-chloro complex (official answer: 5) PDF
  • Q.71 (8 April, shift 2) · Numerical · Magnetic Properties: Count paramagnetic complexes in a given list (official answer: 6) PDF

JEE Main2017

  • Q.50 · MCQ · Werner's Theory: Formula of cobalt complex from chloride ions precipitated PDF

JEE Main2016

  • Q.48 · MCQ · Magnetic Moment: Pair of complexes with same magnetic moment PDF
  • Q.49 · MCQ · Isomerism in Complexes: Complex that shows optical isomerism PDF

Coordination Compounds in other exams

The same chapter in other official papers we tagged: JEE Advanced (28 questions), NEET (2 questions).

Other Chemistry chapters

FAQ

How many Coordination Compounds questions come in JEE Main?

In the official papers we tagged: 15 in 2026 (9 papers), 1 in 2017 (1 paper) and 2 in 2016 (1 paper). That is 18 questions in all, about 6% of Chemistry.

Which Coordination Compounds topics repeat in JEE Main?

Asked in the most papers: Crystal Field Theory, Werner’s Theory, Isomerism in Complexes. The concept table lists every one with its count.

Are these official JEE Main questions?

Yes. Every question is from an official JEE Main paper hosted on our year pages. The one-line summaries are ours; open the PDF linked beside each question for the full text.