11 year papers

Chemical Thermodynamics JEE Main PYQ Chapter Wise

Chemical Thermodynamics JEE Main PYQs: all 14 questions from 11 official papers (2016–2026), by concept with official answers. Asked in 3 of 3 years.

Updated2 min read
Full name
Joint Entrance Examination Main
Conducted by
NTA
Frequency
Multiple sessions per year
Sections
Physics · Chemistry · Mathematics
Official site
jeemain.nta.nic.in ↗

Explore: All JEE Main chapters · JEE Main Chemistry PYQs · JEE Main hub · JEE Main 2026 · Syllabus & pattern

Answer first

Chemical Thermodynamics PYQs (previous year questions) for JEE Main: Chemical Thermodynamics (Chemistry) had 14 questions across the 11 official JEE Main papers we tagged (2016–2026), and appeared in 10 of them. Asked in 3 of 3 years. The concepts asked in the most papers: Hess’s Law, Gibbs Energy, Heat Capacity.

Year-wise question count

Asked in 3 of 3 years.

YearPapersQuestionsPer paper
JEE Main 20269111.2
JEE Main 2017122
JEE Main 2016111

Most-asked concepts

Sorted by the number of papers a concept appeared in.

ConceptQuestionsPapersYears
Hess's Law332026, 2017, 2016
Gibbs Energy222026
Heat Capacity222026
Enthalpy of Formation112026
Enthalpy of Reaction112026
First Law112017
First Law of Thermodynamics112026
Gibbs Energy and Equilibrium112026
Isothermal Processes112026
Work in Isothermal Processes112026

How to practise Chemical Thermodynamics PYQs

  1. Start with the concepts at the top of the table. They have come back the most.
  2. Solve one year’s Chemical Thermodynamics questions from the official PDF against the clock, then check the answer listed below.
  3. Log every miss as a concept gap, a calculation slip or a misread. Each needs a different fix.
  4. Once a concept is clean in two papers, move to the next. Then sit a full paper from the year pages.

Questions by year

Each line gives the question number and paper, type, concept, our one-line summary and the official answer, with a link to the official PDF.

JEE Main2026

  • Q.54 (2 April, shift 1) · MCQ · Hess's Law: Enthalpy of formation of anhydrous Al2Cl6 from given reaction data (official answer: option 4) PDF
  • Q.75 (2 April, shift 1) · Numerical · Gibbs Energy: Transition temperature where Delta G = 105 - 35 log T is zero (official answer: 727) PDF
  • Q.54 (2 April, shift 2) · MCQ · First Law of Thermodynamics: Work in the reverse step of a cyclic process from heat and work data (official answer: option 4) PDF
  • Q.54 (4 April, shift 1) · MCQ · Heat Capacity: Statements on Cv versus Cp and heat in constant volume process (official answer: option 4) PDF
  • Q.71 (4 April, shift 2) · Numerical · Enthalpy of Formation: Enthalpy of formation of ethanol from bomb calorimeter data (official answer: 3) PDF
  • Q.54 (5 April, shift 2) · MCQ · Gibbs Energy: ΔG° of X₂+Y₂ → 2XY at 600 K from ΔH and S data (official answer: option 2) PDF
  • Q.55 (5 April, shift 2) · MCQ · Heat Capacity: Order of molar heat capacities of copper, bromine and helium (official answer: option 2) PDF
  • Q.55 (6 April, shift 1) · MCQ · Work in Isothermal Processes: Order magnitudes of work for single and multistage expansion/compression (official answer: option 3) PDF
  • Q.75 (6 April, shift 1) · Numerical · Gibbs Energy and Equilibrium: Find standard entropy change from enthalpy change and K (official answer: 34) PDF
  • Q.54 (6 April, shift 2) · MCQ · Isothermal Processes: Match isothermal process types with q and w expressions (official answer: option 3) PDF
  • Q.74 (8 April, shift 2) · Numerical · Enthalpy of Reaction: Enthalpy change of H2S combustion from enthalpies of formation (official answer: 1126) PDF

JEE Main2017

  • Q.31 · MCQ · Hess's Law: Enthalpy of formation of methane from given reactions PDF
  • Q.33 · MCQ · First Law: Which work equals change in internal energy PDF

JEE Main2016

  • Q.35 · MCQ · Hess's Law: Heat of formation of CO from combustion enthalpies PDF

Chemical Thermodynamics in other exams

The same chapter in other official papers we tagged: JEE Advanced (23 questions), NEET (3 questions).

Other Chemistry chapters

FAQ

How many Chemical Thermodynamics questions come in JEE Main?

In the official papers we tagged: 11 in 2026 (9 papers), 2 in 2017 (1 paper) and 1 in 2016 (1 paper). That is 14 questions in all, about 5% of Chemistry.

Which Chemical Thermodynamics topics repeat in JEE Main?

Asked in the most papers: Hess’s Law, Gibbs Energy, Heat Capacity. The concept table lists every one with its count.

Are these official JEE Main questions?

Yes. Every question is from an official JEE Main paper hosted on our year pages. The one-line summaries are ours; open the PDF linked beside each question for the full text.